Low Temperature Physics: 38, 723 (2012); https://doi.org/10.1063/1.4745884 (4 pages)
Физика Низких Температур: Том 38, Выпуск 8 (Август 2012), c. 912-916    ( к оглавлению , назад )

Low-temperature phosphorescence of dicyanoacetylene in rare gas solids

Michał Turowski1, Claudine Crépin2, Isabelle Couturier-Tamburelli3, Nathalie Piétri3, and Robert Kołos1,4

1Institute of Physical Chemistry of the Polish Academy of Sciences, 44 Kasprzaka Str., Warsaw 01-224, Poland
E-mail: robert.kolos@ichf.edu.pl

2Institut des Sciences Moléculaires d'Orsay, UMR 8214, Univ Paris- Sud, CNRS, Orsay F-91405, France

3UMR CNRS 6633, Physique des Interactions Ioniques et Moléculaires, Université de Provence, Case 252, Centre de St. Jérôme, 13397 Marseille Cedex 20, France

4Cardinal S. Wyszyński University, Faculty of Mathematics and Natural Sciences Wóycickiego 1/3, Warsaw 01-938, Poland

Received March 12, 2012


A strong visible ã3u+X̃1g+ luminescence was observed upon the UV excitation of cryogenic rare gas (argon, krypton, and xenon) matrices doped with dicyanoacetylene (NC4N). Spectra and lifetimes of this phosphorescence have been measured. A detailed analysis of resolved vibronic bands is presented.

PACS: 33.50.Dq Fluorescence and phosphorescence spectra.

Ключевые слова: matrix isolation, phosphorescence, dicyanoacetylene, cyanopolyynes.